Self-Powered Quasi-Solid-State Photoelectrochemical Photodetectors Based on MXene Paper Modified by ZnO Nanostructured Architecture

Karagoz E., Tuc Altaf C., TUZLUCA YEŞİLBAĞ F. N., YEŞİLBAĞ Y. Ö., Erdem E., Bakan Misirlioglu F., ...Daha Fazla

ACS Applied Nano Materials, cilt.7, sa.7, ss.7709-7719, 2024 (SCI-Expanded) identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 7 Sayı: 7
  • Basım Tarihi: 2024
  • Doi Numarası: 10.1021/acsanm.4c00234
  • Dergi Adı: ACS Applied Nano Materials
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Compendex
  • Sayfa Sayıları: ss.7709-7719
  • Anahtar Kelimeler: MXene, photodetector, photoelectrochemical, ZnO nanorod, ZnO nanowire
  • Erzincan Binali Yıldırım Üniversitesi Adresli: Evet

Özet

In this work, we report a self-powered quasi-solid-state photodetector (PD) device prepared from flexible two-dimensional (2D) nanocomposites of a zinc oxide nanowire (ZnO-NW) in various weight percents (5, 10, 30, 50%) and Ti3C2Tx (MXene) paper, constructed with manganese (Mn)-doped zinc oxide nanorods (ZnO NRs) using an ionic gel electrolyte and carbon paper. All PD performance tests revealed that 5% ZnO-MXene-based devices were superior to the other samples. The maximum detectivity of 1.44 × 1013 Jones at 367 nm (0.1 mW cm-2) and zero bias was calculated for the 5% ZnO-MXene-based device. Additionally, a very high on/off ratio of nearly 106, which is approximately 35-fold higher than that of the 50% ZnO-MXene-based PDs, was achieved for 5% ZnO-MXene PD at a zero bias under 367 nm (2.52 mW cm-2) illumination. The rise time for this device was 9.25 ms. Furthermore, the PD device exhibited excellent stability by enduring 1000 s of light on/off cycles. As a result, a simple, compact, and cost-effective self-powered ZnO-NW:MXene-based PD configuration showed fast photoresponse and excellent detecting performance.