Transient formation of hydrogen tetraoxide from hydrogen peroxide with bis(trifluoroacetoxyiodo)benzene: A chemical generator of singlet oxygen for organic synthesis
SYNLETT, sa.8, ss.1180-1182, 2003 (SCI-Expanded, Scopus)
- Yayın Türü: Makale / Tam Makale
- Cilt numarası: Sayı: 8
- Basım Tarihi: 2003
- Doi Numarası: 10.1055/s-2003-39889
- Dergi Adı: SYNLETT
- Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
- Sayfa Sayıları: ss.1180-1182
- Erzincan Binali Yıldırım Üniversitesi Adresli: Hayır
Özet
Decomposition of hydrogen tetraoxide, produced by the reaction of hydrogen peroxide with bis(trifluoroacetoxyiodo) benzene, generates singlet molecular oxygen. Oxidation of typical organic substrates in an organic solvent through [4+2] cycloaddition and ene reactions have been carried out on a preparative scale.